Is this sentence all right? which sentence is clearer?
I was not able to open the document that you emailed to me.
I could not open the document that you emailed to me.
Both are fine.
You could, by the way, omit "to."
I'm not a teacher, but I write for a living. Please don't ask me about 2nd conditionals, but I'm a safe bet for what reads well in (American) English.