
An addition about "roll-call of London's who's who":
People who enlist in an army are 'en
rolled' - in this case "the roll" is a list of all the relevant people. When a coachful of tourists stops for ten minutes, before they start up again the courier 'calls the roll' - not as formally as in the army.
In the UK (and probably there are lots of spin-offs everywhere else) there is a big book called
Who's Who:
Who's Who (UK - Wikipedia, the free encyclopedia) . I imagine this book is the source of the expression "a Who's Who", meaning a list of notable people - (I 'hear' the capital
Ws, even when they're not there.

)
So the meaning of the whole phrase is, as Anglika said, 'everyone who is anyone [in the Daily Mail gossip columnist's view]'.
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