The point about prepositions is that, in addition to a 'core' meaning or two, many can be used in dozens of idiosyncratic ways. It is far more useful for learners to note the phrases in which they are used rather than try to pin down the precise meaning of the prepositions within the phrases.
It doesn't. He's to home means nothing to me.
Could you explain more?Maybe it's used some places instead of at home. i wouldn't worry about it too much.