Thank you!
Do you think it will be better if the question is "What is that boy"?
That would be unnatural. In general, we use "Who" for people and "What" for things. If you asked "What does that boy do?", you'd get "He's a student". If you asked "Who's that boy?" you might get his name, or his relationship to the person you asked, or some other information (as in post #1).
Who's that boy?
That's Samuel.
Who's that boy?
That's my cousin Samuel.
Who's that boy?
He's a student in my year but I don't know his name.