[Vocabulary] Throw sth in sb vs throw sth at sb vs throw sth against sb

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ChessEnthusiast

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What's worse, the rebels threw petrol bombs in/at/against the police.

Which one suits this sentence best?
 
(not a teacher)
"At" is definitely correct here, the other options probably are not. Let's wait what the experts say.
"Against" could be used in a sentence like "They protested against the police."
 
Only at works there.
 
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